Glasses and glass-ceramics in the SrO-TiO2-Al2O3-SiO2-B2O3 system and the effect of P2O5 additions

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dc.contributor.authorBengisu, Murat
dc.contributor.authorBrow, Richard K.
dc.contributor.authorWittenauer, Andrew
dc.date.accessioned2026-02-06T18:34:30Z
dc.date.issued2008
dc.departmentDoğu Akdeniz Üniversitesi
dc.description.abstractThe glass formation abilities of various compositions in SrO-TiO2-Al2O3-SiO2, SrO-TiO2-B2O3-SiO2, SrO-TiO2-Al2O3-B2O3, and SrO-TiO2-Al2O3-SiO2-B2O3 systems were studied. Many new compositions were found to be suitable for the casting of crack-free, optically clear glasses of different color and with glass transition temperatures ranging from 595 to 775 C. The crystallization behavior, structure, and thermal expansion behavior of selected glasses were analyzed by DTA, XRD, dilatometry, and heat treatment. The effect of P2O5 on the glass structure and crystallization behavior was also studied. P2O5 played a dual role depending on composition. In some glasses it acted as a nucleating agent while in others it suppressed crystallization. Heat treatment of borate and borosilicate glasses transformed them into glass-ceramics while comparable SrO-TiO2-Al2O3-SiO2 glasses showed a lower tendency to crystallize and form glass-ceramics under the same conditions.
dc.identifier.doi10.1007/s10853-008-2541-1
dc.identifier.endpage3538
dc.identifier.issn0022-2461
dc.identifier.issn1573-4803
dc.identifier.issue10
dc.identifier.scopus2-s2.0-42149085738
dc.identifier.scopusqualityQ1
dc.identifier.startpage3531
dc.identifier.urihttps://doi.org/10.1007/s10853-008-2541-1
dc.identifier.urihttps://hdl.handle.net/11129/11822
dc.identifier.volume43
dc.identifier.wosWOS:000254964200027
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Materials Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20260204
dc.subjectDielectric-Properties
dc.subjectCrystallization
dc.subjectBehavior
dc.subjectMicrostructure
dc.subjectNucleation
dc.titleGlasses and glass-ceramics in the SrO-TiO2-Al2O3-SiO2-B2O3 system and the effect of P2O5 additions
dc.typeArticle

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